| 1. | EXECUTIVE SUMMARY |
| 1.1. | What are bioplastics? |
| 1.2. | Global supply of plastics will continue to grow exponentially |
| 1.3. | Bioplastics in the circular economy |
| 1.4. | Environmental costs: the rising tide of plastic pollution |
| 1.5. | Navigating biobased polymers from monosaccharides |
| 1.6. | Navigating biobased polymers from vegetable oils |
| 1.7. | Synthetic biobased polymers and monomers: key companies |
| 1.8. | Naturally occurring biobased polymers: key companies |
| 1.9. | Polylactic acid (PLA) |
| 1.10. | PET and PEF |
| 1.11. | Other synthetic biobased polymers |
| 1.12. | Polyamide properties, applications and opportunities |
| 1.13. | Polyhydroxyalkanoates (PHA) |
| 1.14. | Polysaccharides |
| 1.15. | Effects of Brent crude prices on the bioplastic industry |
| 1.16. | Out of the valley of death: bioplastics becoming productive |
| 1.17. | Bioplastics: technology readiness level |
| 1.18. | Rising feedstock prices |
| 1.19. | Bioplastics global total capacity forecast 2023-2033 |
| 2. | INTRODUCTION |
| 2.1. | Scope of the report |
| 2.2. | Key terms and definitions |
| 2.3. | What are bioplastics? |
| 2.4. | Global supply of plastics will continue to grow exponentially |
| 2.5. | Decarbonizing economies |
| 2.6. | Bioplastics in the circular economy |
| 2.7. | Environmental costs: the rising tide of plastic pollution |
| 2.8. | The plastic waste management pyramid |
| 2.9. | Recycling polymers |
| 2.10. | What does "biodegradable" mean? |
| 2.11. | The three main families of bioplastics |
| 2.12. | Polymer types: thermoplastics, thermosets and elastomers |
| 2.13. | The range of available biobased monomers |
| 2.14. | Navigating biobased polymers from monosaccharides |
| 2.15. | Navigating biobased polymers from vegetable oils |
| 2.16. | The four drivers for substitution |
| 2.17. | The Green Premium |
| 2.18. | Effect of the price of Brent crude on the bioplastics industry |
| 2.19. | Out of the valley of death: bioplastics becoming productive |
| 2.20. | Bioplastics: technology readiness level |
| 2.21. | Rising feedstock prices |
| 2.22. | Plastic regulation around the world |
| 2.23. | Food, land, and water competition |
| 2.24. | Green transition: the chain of custody |
| 2.25. | Chain of custody: mass balance (1) |
| 2.26. | Chain of custody: mass balance (2) |
| 3. | BIOBASED SYNTHETIC POLYMERS: POLYLACTIC ACID (PLA) |
| 3.1. | What is polylactic acid? |
| 3.2. | Production of PLA |
| 3.3. | PLA production process |
| 3.4. | Lactic acid: bacterial fermentation or chemical synthesis? |
| 3.5. | Optimal lactic acid bacteria strains for fermentation |
| 3.6. | Engineering yeast strains for lactic acid fermentation |
| 3.7. | Fermentation, recovery and purification |
| 3.8. | Polymerization of lactide and microstructures of PLA |
| 3.9. | PLA end-of-life options |
| 3.10. | Hydrolysis of PLA |
| 3.11. | Suppliers of lactide and polylactic acid |
| 3.12. | Current and future applications of polylactic acid |
| 3.13. | Polylactic acid: a SWOT analysis |
| 3.14. | Opportunities in the lifecycle of PLA |
| 3.15. | TotalEnergies Corbion |
| 3.16. | Natureworks |
| 3.17. | BASF: ecovio® |
| 3.18. | Conclusions |
| 4. | BIOBASED SYNTHETIC POLYMERS: OTHER SYNTHETIC BIOBASED POLYESTERS |
| 4.1. | Introduction to polyesters from diacids and diols |
| 4.2. | The range of available biobased polyesters |
| 4.3. | Biobased polyester suppliers |
| 4.4. | Polyethylene terephthalate (PET) |
| 4.5. | Biobased MEG and PET: monomer production |
| 4.6. | Biobased MEG and PET: industry & applications |
| 4.7. | Biobased MEG and PET: SWOT |
| 4.8. | Biobased PDO and PTT: monomer production |
| 4.9. | Biobased PDO and PTT: polymer applications |
| 4.10. | Biobased BDO: monomer production |
| 4.11. | Biobased BDO technology is licenced from Genomatica |
| 4.12. | Biobased BDO and PBT: polymer applications |
| 4.13. | Biobased terephthalic acid (TPA) |
| 4.14. | Biobased succinic acid: monomer production |
| 4.15. | Biobased succinic acid and PBS: polymer applications |
| 4.16. | Polyethylene furanoate (PEF) |
| 4.17. | Biobased furfural compounds: 5-HMF |
| 4.18. | Biobased FDCA: monomer production |
| 4.19. | Biobased FDCA and PEF: polymer applications |
| 5. | BIOBASED SYNTHETIC POLYMERS: POLYAMIDES |
| 5.1. | Introduction to biobased polyamides |
| 5.2. | Biobased synthesis routes to polyamides |
| 5.3. | Range of available biobased monomers and polyamides |
| 5.4. | Biobased monomer and polyamide suppliers |
| 5.5. | C6: adipic acid, hexamethylenediamine and caprolactam |
| 5.6. | C10: sebacic acid and decamethylenediamine |
| 5.7. | C11: 11-aminoundecanoic acid |
| 5.8. | C12: Dodecanedioic acid |
| 5.9. | Polyamide properties, applications and opportunities |
| 6. | BIOBASED SYNTHETIC POLYMERS: OTHER SYNTHETIC BIOBASED POLYMERS |
| 6.1. | Polyester polyols, polyurethanes and polyisocyanates |
| 6.2. | Cargill: vegetable oil derived polyols |
| 6.3. | Covestro and Reverdia: Impranil eco Succinic acid based polyester polyols |
| 6.4. | BASF: Sovermol 830 Castor oil derived polyether-ester polyol |
| 6.5. | Covestro: PDI and Desmodur eco polyisocyanurate |
| 6.6. | Biobased naphtha |
| 6.7. | Biobased polyolefins |
| 6.8. | Biobased polyolefins: challenging but in demand |
| 6.9. | Biobased polyolefins Landscape |
| 6.10. | Braskem: I'm green polyethylene |
| 6.11. | Borealis: Bornewables |
| 6.12. | Biobased isosorbide as a comonomer |
| 6.13. | Roquette: POLYSORB isosorbide |
| 6.14. | Mitsubishi Chemical Corporation: Durabio |
| 7. | NATURALLY OCCURRING BIOPLASTICS AND BIOBASED POLYMERS: POLYHYDROXYALKANOATES (PHA) |
| 7.1. | Introduction to poly(hydroxyalkanoates) |
| 7.2. | Key commercial PHAs and microstructures |
| 7.3. | Properties of commercial PHAs |
| 7.4. | Suppliers of PHAs |
| 7.5. | PHB, PHBV, and P(3HB-co-4HB) |
| 7.6. | Short and medium chain length PHAs |
| 7.7. | Biosynthetic pathways to PHAs |
| 7.8. | Fermentation, recovery and purification |
| 7.9. | PHAs: a SWOT analysis |
| 7.10. | Applications of PHAs |
| 7.11. | Opportunities in PHAs |
| 7.12. | Reducing the cost of PHA production |
| 7.13. | Risks in PHAs |
| 7.14. | PHAs are only made in small quantities |
| 7.15. | PHA production facilities |
| 7.16. | Newlight Technologies |
| 7.17. | Danimer Scientific |
| 7.18. | Conclusions |
| 8. | NATURALLY OCCURRING BIOPLASTICS AND BIOBASED POLYMERS: POLYSACCHARIDES |
| 8.1. | Cellulose |
| 8.2. | Nanocellulose |
| 8.3. | Nanocellulose up close |
| 8.4. | Forms of nanocellulose |
| 8.5. | Applications of nanocellulose |
| 8.6. | Celluforce |
| 8.7. | Weidmann Fiber Technology |
| 8.8. | Exilva |
| 8.9. | Starch |
| 8.10. | Manufacturing thermoplastic starch (TPS) |
| 8.11. | Composite and modified thermoplastic starches |
| 8.12. | Plantic |
| 8.13. | Novamont |
| 8.14. | Seaweeds |
| 8.15. | Seaweed polymers for packaging |
| 8.16. | Loliware |
| 8.17. | Notpla: Ooho! |
| 8.18. | Evoware |
| 8.19. | Constraints for polysaccharide bioplastics |
| 9. | MARKETS AND FORECASTS |
| 9.1. | Global total plastic production continues to grow 2.6% year on year |
| 9.2. | Global production capacities of bioplastics by region (2021) |
| 9.3. | Bioplastics: processability |
| 9.4. | Bioplastics: application in packaging |
| 9.5. | Bioplastics: applicability for flexible packaging |
| 9.6. | Bioplastics: applicability for rigid packaging |
| 9.7. | Bioplastics and automotive applications |
| 9.8. | Bioplastics agriculture and textile applications |
| 9.9. | Methodology |
| 9.10. | Bioplastics global total capacity vs overall plastics capacity forecast 2023-2033 |
| 9.11. | Bioplastics global total capacity forecast 2023-2033 |
| 9.12. | Bioplastics global total capacity forecast 2023-2033 |
| 9.13. | Polylactic acid (PLA) global capacity forecast 2023-2033 |
| 9.14. | PET and PEF global capacity forecast 2023-2033 |
| 9.15. | Other polyesters global capacity forecast2023-2033 |
| 9.16. | Polyamides and other synthetic polymers global capacity forecast 2023-2033 |
| 9.17. | PHAs global capacity forecast 2023-2033 |
| 9.18. | Polysaccharides global capacity forecast 2023-2033 |